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Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
The synthesis of interconnected nanoporous carbon (NPC) material from direct annealing of ultra-small Al-based metal–organic complex (Al-MOC) has been demonstrated. NPC presents a large accessible area of 1054 m(2)/g, through the Methylene Blue (MB) adsorption method, which is comparable to the high...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523955/ https://www.ncbi.nlm.nih.gov/pubmed/30979046 http://dx.doi.org/10.3390/nano9040601 |
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author | Shi, Xiaoze Zhang, Shuai Chen, Xuecheng Mijowska, Ewa |
author_facet | Shi, Xiaoze Zhang, Shuai Chen, Xuecheng Mijowska, Ewa |
author_sort | Shi, Xiaoze |
collection | PubMed |
description | The synthesis of interconnected nanoporous carbon (NPC) material from direct annealing of ultra-small Al-based metal–organic complex (Al-MOC) has been demonstrated. NPC presents a large accessible area of 1054 m(2)/g, through the Methylene Blue (MB) adsorption method, which is comparable to the high specific surface area (SSA) of 1593 m(2)/g, through an N(2) adsorption/desorption analysis. The adsorption properties and mechanisms were tested by various dye concentrations, pH, and temperature conditions. The high MB accessible area and the good electrical conductivity of the interconnected NPC, led to a large specific capacitance of 205 F/g, with a potential window from 0 to 1.2 V, in a symmetric supercapacitor, and a large energy density of 10.25 Wh/kg, in an aqueous electrolyte, suggesting a large potential in supercapacitors. |
format | Online Article Text |
id | pubmed-6523955 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-65239552019-06-03 Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor Shi, Xiaoze Zhang, Shuai Chen, Xuecheng Mijowska, Ewa Nanomaterials (Basel) Article The synthesis of interconnected nanoporous carbon (NPC) material from direct annealing of ultra-small Al-based metal–organic complex (Al-MOC) has been demonstrated. NPC presents a large accessible area of 1054 m(2)/g, through the Methylene Blue (MB) adsorption method, which is comparable to the high specific surface area (SSA) of 1593 m(2)/g, through an N(2) adsorption/desorption analysis. The adsorption properties and mechanisms were tested by various dye concentrations, pH, and temperature conditions. The high MB accessible area and the good electrical conductivity of the interconnected NPC, led to a large specific capacitance of 205 F/g, with a potential window from 0 to 1.2 V, in a symmetric supercapacitor, and a large energy density of 10.25 Wh/kg, in an aqueous electrolyte, suggesting a large potential in supercapacitors. MDPI 2019-04-11 /pmc/articles/PMC6523955/ /pubmed/30979046 http://dx.doi.org/10.3390/nano9040601 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Shi, Xiaoze Zhang, Shuai Chen, Xuecheng Mijowska, Ewa Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor |
title | Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor |
title_full | Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor |
title_fullStr | Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor |
title_full_unstemmed | Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor |
title_short | Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor |
title_sort | evaluation of nanoporous carbon synthesized from direct carbonization of a metal–organic complex as a highly effective dye adsorbent and supercapacitor |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523955/ https://www.ncbi.nlm.nih.gov/pubmed/30979046 http://dx.doi.org/10.3390/nano9040601 |
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