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Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor

The synthesis of interconnected nanoporous carbon (NPC) material from direct annealing of ultra-small Al-based metal–organic complex (Al-MOC) has been demonstrated. NPC presents a large accessible area of 1054 m(2)/g, through the Methylene Blue (MB) adsorption method, which is comparable to the high...

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Detalles Bibliográficos
Autores principales: Shi, Xiaoze, Zhang, Shuai, Chen, Xuecheng, Mijowska, Ewa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523955/
https://www.ncbi.nlm.nih.gov/pubmed/30979046
http://dx.doi.org/10.3390/nano9040601
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author Shi, Xiaoze
Zhang, Shuai
Chen, Xuecheng
Mijowska, Ewa
author_facet Shi, Xiaoze
Zhang, Shuai
Chen, Xuecheng
Mijowska, Ewa
author_sort Shi, Xiaoze
collection PubMed
description The synthesis of interconnected nanoporous carbon (NPC) material from direct annealing of ultra-small Al-based metal–organic complex (Al-MOC) has been demonstrated. NPC presents a large accessible area of 1054 m(2)/g, through the Methylene Blue (MB) adsorption method, which is comparable to the high specific surface area (SSA) of 1593 m(2)/g, through an N(2) adsorption/desorption analysis. The adsorption properties and mechanisms were tested by various dye concentrations, pH, and temperature conditions. The high MB accessible area and the good electrical conductivity of the interconnected NPC, led to a large specific capacitance of 205 F/g, with a potential window from 0 to 1.2 V, in a symmetric supercapacitor, and a large energy density of 10.25 Wh/kg, in an aqueous electrolyte, suggesting a large potential in supercapacitors.
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spelling pubmed-65239552019-06-03 Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor Shi, Xiaoze Zhang, Shuai Chen, Xuecheng Mijowska, Ewa Nanomaterials (Basel) Article The synthesis of interconnected nanoporous carbon (NPC) material from direct annealing of ultra-small Al-based metal–organic complex (Al-MOC) has been demonstrated. NPC presents a large accessible area of 1054 m(2)/g, through the Methylene Blue (MB) adsorption method, which is comparable to the high specific surface area (SSA) of 1593 m(2)/g, through an N(2) adsorption/desorption analysis. The adsorption properties and mechanisms were tested by various dye concentrations, pH, and temperature conditions. The high MB accessible area and the good electrical conductivity of the interconnected NPC, led to a large specific capacitance of 205 F/g, with a potential window from 0 to 1.2 V, in a symmetric supercapacitor, and a large energy density of 10.25 Wh/kg, in an aqueous electrolyte, suggesting a large potential in supercapacitors. MDPI 2019-04-11 /pmc/articles/PMC6523955/ /pubmed/30979046 http://dx.doi.org/10.3390/nano9040601 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Shi, Xiaoze
Zhang, Shuai
Chen, Xuecheng
Mijowska, Ewa
Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
title Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
title_full Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
title_fullStr Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
title_full_unstemmed Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
title_short Evaluation of Nanoporous Carbon Synthesized from Direct Carbonization of a Metal–Organic Complex as a Highly Effective Dye Adsorbent and Supercapacitor
title_sort evaluation of nanoporous carbon synthesized from direct carbonization of a metal–organic complex as a highly effective dye adsorbent and supercapacitor
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6523955/
https://www.ncbi.nlm.nih.gov/pubmed/30979046
http://dx.doi.org/10.3390/nano9040601
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