Molecular interaction studies of binary systems comprising [C(2)mim] [BF(4)] with ethyl acetoacetate or benzaldehyde

In this work, new data for the binary mixtures containing 1-ethyl-3-methylimidazolium tetrafluoroborate ([C(2)mim] [BF(4)]) ionic liquid (IL) with benzaldehyde or ethyl acetoacetate were investigated under atmospheric pressure (p = 0.1 MPa) and at temperatures (293.15–313.15) K. The binary mixtures were completely miscible at all proportions. Densities ([Formula: see text]), viscosities ([Formula: see text]) as well as speeds of sound [Formula: see text] were conducted across the entire range of mole fraction ([Formula: see text] = 0 to 1). The excess properties which include excess molar volumes [Formula: see text] , intermolecular free length ([Formula: see text]), deviations in viscosity ([Formula: see text]), isentropic compressibility [Formula: see text] , apparent molar isentropic compressibility ([Formula: see text]) as well as deviation in isentropic compressibility [Formula: see text] were determined from the experimentally found results of speed of sound, viscosity and density. The obtained derived properties have been elucidated in terms of solute-solvent interactions taking place in the systems. The investigation of thermophysical properties of organic solvents with ionic liquids is essential as they decide the transformation of ionic liquids from small laboratory scale to large industrial applications. The obtained results are important and essential as they describe the molecular interactions, and can be used in constructing the structure-property correlation as well as molecular modelling that exist between [C(2)mim] [BF(4)] with benzaldehyde or ethyl acetoacetate. Redlich-Kister polynomial equation was used to fit the excess values and a good correlation was achieved.