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Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes

The one-electron reduction of (CAAC(Me))BCl(3) (CAAC(Me) = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) yields the dichloroboryl radical [(CAAC(Me))BCl(2)]˙. Furthermore, the twofold reduction of (CAAC(Me))BCl(3) in the presence of a range of Lewis bases (L = CAAC(Me), N-hetero...

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Detalles Bibliográficos
Autores principales:	Arrowsmith, Merle, Schweizer, Julia I., Heinz, Myron, Härterich, Marcel, Krummenacher, Ivo, Holthausen, Max C., Braunschweig, Holger
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6531816/ https://www.ncbi.nlm.nih.gov/pubmed/31183061 http://dx.doi.org/10.1039/c9sc01039d

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