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Quantifying rival bond fission probabilities following photoexcitation: C–S bond fission in t-butylmethylsulfide

We illustrate a new, collision-free experimental strategy that allows determination of the absolute probabilities of rival bond fission processes in a photoexcited molecule – here t-butylmethylsulfide (BSM). The method combines single photon (‘universal’) ionization laser probe methods, simultaneous...

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Detalles Bibliográficos
Autores principales: Bain, Matthew, Hansen, Christopher S., Karsili, Tolga N. V., Ashfold, Michael N. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540878/
https://www.ncbi.nlm.nih.gov/pubmed/31191885
http://dx.doi.org/10.1039/c9sc00738e

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