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1-Titanacyclobuta-2,3-diene – an elusive four-membered cyclic allene

The synthesis of an unusual 1-metalla-2,3-cyclobutadiene complex [rac-(ebthi)Ti(Me(3)SiC(3)SiMe(3))] (rac-ebthi = rac-1,2-ethylene-1,1′-bis(η(5)-tetrahydroindenyl)), a formal metallacyclic analogue of a non-existent four-membered 1,2-cyclobutadiene, is described. By variation of the cyclopentadienyl...

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Detalles Bibliográficos
Autores principales:	Reiß, Fabian, Reiß, Melanie, Bresien, Jonas, Spannenberg, Anke, Jiao, Haijun, Baumann, Wolfgang, Arndt, Perdita, Beweries, Torsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540905/ https://www.ncbi.nlm.nih.gov/pubmed/31191888 http://dx.doi.org/10.1039/c9sc01002e

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