Cargando…

Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations

We report herein the exploitment of the partially fluorinated trifluoroethyl as precatalyst ligands in nickel-catalyzed Suzuki-type alkylation and fluoroalkylation coupling reactions. Compared with the [L(n)Ni(II)(aryl)(X)] precatalysts, the unique characters of bis-trifluoroethyl ligands imparted p...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yang, Yi, Zhou, Qinghai, Cai, Junjie, Xue, Teng, Liu, Yingle, Jiang, Yan, Su, Yumei, Chung, Lungwa, Vicic, David A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540912/ https://www.ncbi.nlm.nih.gov/pubmed/31191883 http://dx.doi.org/10.1039/c9sc00554d

Ejemplares similares

Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
por: Guo, Lin, et al.
Publicado: (2019)

Bench-Stable Nickel Precatalysts with Heck-type Activation
por: Weber, Jessica M., et al.
Publicado: (2018)

Nickel-catalyzed migratory alkyl–alkyl cross-coupling reaction
por: Li, Yangyang, et al.
Publicado: (2020)

Nickel-Catalyzed Suzuki Coupling of Phenols Enabled by SuFEx of Tosyl Fluoride
por: Wang, Huimin, et al.
Publicado: (2023)

Boric acid as a precatalyst for BH(3)-catalyzed hydroboration
por: Légaré Lavergne, Julien, et al.
Publicado: (2021)

Nickel-Catalyzed Carbonylative Synthesis of Functionalized Alkyl Iodides
por: Peng, Jin-Bao, et al.
Publicado: (2018)

Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
por: Li, Yuqiang, et al.
Publicado: (2020)

Bulky Di(1-adamantyl)phosphinous Acid-Ligated Pd(II) Precatalysts for Suzuki Reactions of Unreactive Aryl Chlorides
por: Xiao, He-Xin, et al.
Publicado: (2021)

Sterically and Electronically Modified Aryliminopyridyl-Nickel Bromide Precatalysts for an Access to Branched Polyethylene with Vinyl/Vinylene End Groups
por: Zada, Muhammad, et al.
Publicado: (2020)

Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides
por: Fang, Yi, et al.
Publicado: (2018)

Nickel-catalyzed alkyl-arylation of 3,3,3-trifluoropropene
por: Xu, Chang, et al.
Publicado: (2022)

Highly E-Selective, Stereoconvergent Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Alkenyl Ethers
por: Ho, Guo-Ming, et al.
Publicado: (2019)

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst
por: Friis, Stig D., et al.
Publicado: (2014)

Iron porphyrin-catalyzed N-trifluoroethylation of anilines with 2,2,2-trifluoroethylamine hydrochloride in aqueous solution
por: Ren, Shuang, et al.
Publicado: (2021)

Nickel-catalyzed reductive coupling of unactivated alkyl bromides and aliphatic aldehydes
por: Cruz, Cole L., et al.
Publicado: (2021)

Nickel-Catalyzed Stereoselective Coupling Reactions of Benzylic and Alkyl Alcohol Derivatives
por: Herbert, Claire A., et al.
Publicado: (2023)

Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst
por: Cheung, Chi Wai, et al.
Publicado: (2014)

Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions
por: Eastwood, Jonathan B., et al.
Publicado: (2023)

Nickel–Alkyl Complexes with a Reactive PNC‐Pincer Ligand
por: Jongbloed, Linda S., et al.
Publicado: (2018)

Exploiting the Chiral Ligands of Bis(imidazolinyl)- and Bis(oxazolinyl)thiophenes—Synthesis and Application in Cu-Catalyzed Friedel–Crafts Asymmetric Alkylation
por: Islam, Mohammad Shahidul, et al.
Publicado: (2021)

Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling in a Green Alcohol Solvent for an Undergraduate Organic Chemistry Laboratory
por: Hie, Liana, et al.
Publicado: (2014)

Visible-light-induced nickel-catalyzed α-hydroxytrifluoroethylation of alkyl carboxylic acids: Access to trifluoromethyl alkyl acyloins
por: Chen, Feng, et al.
Publicado: (2023)

Enantioselective Csp3-Csp3 formation by nickel-catalyzed enantioconvergent cross-electrophile alkyl-alkyl coupling of unactivated alkyl halides
por: Zhao, Wen-Tao, et al.
Publicado: (2023)

Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols
por: Ngamnithiporn, Aurapat, et al.
Publicado: (2018)

Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
por: Lv, Leiyang, et al.
Publicado: (2019)

Nickel-Catalyzed Decarbonylative Alkylation of Aroyl Fluorides Assisted by Lewis-Acidic Organoboranes
por: Okuda, Yasuhiro, et al.
Publicado: (2018)

Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
por: Lin, Tingzhi, et al.
Publicado: (2020)

Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO(2)
por: Sun, Guo-Quan, et al.
Publicado: (2021)

Electrochemical Nickel-Catalyzed C(sp(3))–C(sp(3)) Cross-Coupling of Alkyl Halides with Alkyl Tosylates
por: Ibrahim, Malek Y. S., et al.
Publicado: (2023)

Synthesis of aryldifluoromethyl aryl ethers via nickel-catalyzed suzuki cross-coupling between aryloxydifluoromethyl bromides and boronic acids
por: Lu, Heng, et al.
Publicado: (2022)

Improved Metathesis Lifetime: Chelating Pyridinyl-Alcoholato Ligands in the Second Generation Grubbs Precatalyst
por: du Toit, Jean I., et al.
Publicado: (2014)

Iron(II) Active Species in Iron–Bisphosphine Catalyzed Kumada and Suzuki–Miyaura Cross-Couplings of Phenyl Nucleophiles and Secondary Alkyl Halides
por: Daifuku, Stephanie L., et al.
Publicado: (2015)

Metabolism and toxicity of 2,2,2-trifluoroethyl vinyl ether.
por: Fiserova-Bergerova, V
Publicado: (1977)

Nickel-catalyzed reductive cleavage of aryl alkyl ethers to arenes in absence of external reductant
por: Tobisu, Mamoru, et al.
Publicado: (2015)

Nickel-catalyzed allylic carbonylative coupling of alkyl zinc reagents with tert-butyl isocyanide
por: Weng, Yangyang, et al.
Publicado: (2020)

Nickel(ii)-catalyzed reductive silylation of alkenyl methyl ethers for the synthesis of alkyl silanes
por: Qiu, Xiaodong, et al.
Publicado: (2021)

Ligand-free nickel catalyzed perfluoroalkylation of arenes and heteroarenes
por: Deolka, Shubham, et al.
Publicado: (2022)

Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes
por: Ding, Chao, et al.
Publicado: (2023)

trans-Dichlorobis(XPhos)palladium(II) Precatalyst for Suzuki–Miyaura Cross-Coupling Reactions of Aryl/Vinyl Sulfonates/Halides: Scope, Mechanistic Study, and Synthetic Applications
por: Sirindil, Fatih, et al.
Publicado: (2021)

Nickel-catalyzed C–H alkylation of indoles with unactivated alkyl chlorides: evidence of a Ni(i)/Ni(iii) pathway
por: Pandey, Dilip K., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_kun8hrb3k927u8vvr2a8htqpu5