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Extending mechanochemical porphyrin synthesis to bulkier aromatics: tetramesitylporphyrin
Aldehydes with bulky substituents in the ortho-positions have been historically difficult in porphyrin synthesis, presumably owing to steric hindrance around the reactive site. We have used mechanochemistry for the simple, room-temperature synthesis of tetra-meso-substituted porphyrins. In the prese...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6541328/ https://www.ncbi.nlm.nih.gov/pubmed/31164951 http://dx.doi.org/10.3762/bjoc.15.111 |