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Self-Assembled Porous-Silica within N-Doped Carbon Nanofibers as Ultra-flexible Anodes for Soft Lithium Batteries
Silica is an attractive anode material for soft lithium batteries owing to its high specific capacity, but it suffers severe problems of large volume change and unstable solid-electrolyte interface. Moreover, it is a challenge to fabricate flexible silica anodes. Here, we report a low-cost and scala...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6545390/ https://www.ncbi.nlm.nih.gov/pubmed/31158691 http://dx.doi.org/10.1016/j.isci.2019.05.023 |
Sumario: | Silica is an attractive anode material for soft lithium batteries owing to its high specific capacity, but it suffers severe problems of large volume change and unstable solid-electrolyte interface. Moreover, it is a challenge to fabricate flexible silica anodes. Here, we report a low-cost and scalable strategy to create flexible anodes of N-doped carbon nanofiber-confined porous silica (p-SiO(2)@N-CNF) by developing a sol-gel electrospinning process followed by carbonization. This approach causes the p-SiO(2) nanoparticles (NPs) to be self-assembled within the N-CNFs, which act like elastomer and electrolyte barrier to accommodate volume changes and to enhance the stability of SiO(2), whereas the NPs act as soft plasticizer providing strength to the CNF skeletons. Benefiting from the hierarchical structures, the anodes with high p-SiO(2) loadings (>1.6 mg/cm(2)) exhibit exceptional cycling performance (>1,000 cycles) in terms of bending, current rate, and capacity. Moreover, the batteries remain stable when discharging at 0.5 C and charging at 2 C. |
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