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A Cyanide‐Free Synthesis of Acylcyanides through Ru‐Catalyzed C(sp(3))‐H‐Oxidation of Benzylic Nitriles
A practical method for generation of acylcyanides devoid of any external cyanide sources is presented that relies on a mild Ru‐catalyzed selective C−H‐oxidation of benzylic nitriles. The starting materials are smoothly generated through condensation of the corresponding carboxylic acid amides using...
Autores principales: | Eisele, Pascal, Bauder, Michael, Hsu, Shih‐Fan, Plietker, Bernd |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6547944/ https://www.ncbi.nlm.nih.gov/pubmed/31172005 http://dx.doi.org/10.1002/open.201900130 |
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