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Metal vs. ligand protonation and the alleged proton-shuttling role of the azadithiolate ligand in catalytic H(2) formation with FeFe hydrogenase model complexes

Electron and proton transfer reactions of diiron complexes [Fe(2)adt(CO)(6)] (1) and [Fe(2)adt(CO)(4)(PMe(3))(2)] (4), with the biomimetic azadithiolate (adt) bridging ligand, have been investigated by real-time IR- and UV-vis-spectroscopic observation to elucidate the role of the adt-N as a potenti...

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Detalles Bibliográficos
Autores principales:	Aster, Alexander, Wang, Shihuai, Mirmohades, Mohammad, Esmieu, Charlène, Berggren, Gustav, Hammarström, Leif, Lomoth, Reiner
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6552503/ https://www.ncbi.nlm.nih.gov/pubmed/31293742 http://dx.doi.org/10.1039/c9sc00876d

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