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Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides

Geometrically flexible 9-borabicyclo[3.3.1]nonyl units within the secondary coordination sphere enable isolation of high-spin Fe(ii)-dihydrides stabilized by boron–hydride interactions and a rare example of an isolable S = 3/2 reduction product. The borane-capped Fe(ii)-dihydride: (1) rapidly deprot...

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Detalles Bibliográficos
Autores principales:	Kiernicki, John J., Shanahan, James P., Zeller, Matthias, Szymczak, Nathaniel K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6553361/ https://www.ncbi.nlm.nih.gov/pubmed/31293738 http://dx.doi.org/10.1039/c9sc00561g

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