Dataset on synthesis and crystallographic structure of phenyl(TMP)iodonium(III) acetate

The data in this article are related to research article ‘‘Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium (III) reagents (Koseki et al., 2019). For the title compound, phenyl(2,4,6-trimethoxyphenyl)iodonium(III) acetate (Ph(TMP)IOAc), the single-crystal X-ray...

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Detalles Bibliográficos
Autores principales: China, Hideyasu, Koseki, Daichi, Samura, Kazuki, Kikushima, Kotaro, In, Yasuko, Dohi, Toshifumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6562192/
https://www.ncbi.nlm.nih.gov/pubmed/31211208
http://dx.doi.org/10.1016/j.dib.2019.104063
Descripción
Sumario:The data in this article are related to research article ‘‘Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium (III) reagents (Koseki et al., 2019). For the title compound, phenyl(2,4,6-trimethoxyphenyl)iodonium(III) acetate (Ph(TMP)IOAc), the single-crystal X-ray diffraction measurement together with NMR analysis, like also the method of synthesis and crystallization are presented. The X-ray structure analysis has revealed that the two types of geometries regarding the acetate anion attached to phenyl (TMP)iodonium (III) cation are found in the crystal states.

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