Cargando…

The origin of extrathermodynamic compensations

The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is suggested. A validity of such approach was verified by the example of studying of extrathermodynamic compensations. Several types of exact linear extrathermodynamic compensations as well as their...

Descripción completa

Detalles Bibliográficos
Autores principales: Khakhel', Oleg A., Romashko, Tamila P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6562324/
https://www.ncbi.nlm.nih.gov/pubmed/31211257
http://dx.doi.org/10.1016/j.heliyon.2019.e01839
Descripción
Sumario:The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is suggested. A validity of such approach was verified by the example of studying of extrathermodynamic compensations. Several types of exact linear extrathermodynamic compensations as well as their peculiar type, which peculiarity is indefinable compensation temperature, are established. The criteria that specify these types are stated. These results are illustrated by the identified exact extrathermodynamic compensations in formation of pyrene excimers.