The origin of extrathermodynamic compensations

The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is suggested. A validity of such approach was verified by the example of studying of extrathermodynamic compensations. Several types of exact linear extrathermodynamic compensations as well as their...

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Detalles Bibliográficos
Autores principales: Khakhel', Oleg A., Romashko, Tamila P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6562324/
https://www.ncbi.nlm.nih.gov/pubmed/31211257
http://dx.doi.org/10.1016/j.heliyon.2019.e01839
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author Khakhel', Oleg A.
Romashko, Tamila P.
author_facet Khakhel', Oleg A.
Romashko, Tamila P.
author_sort Khakhel', Oleg A.
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description The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is suggested. A validity of such approach was verified by the example of studying of extrathermodynamic compensations. Several types of exact linear extrathermodynamic compensations as well as their peculiar type, which peculiarity is indefinable compensation temperature, are established. The criteria that specify these types are stated. These results are illustrated by the identified exact extrathermodynamic compensations in formation of pyrene excimers.
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spelling pubmed-65623242019-06-17 The origin of extrathermodynamic compensations Khakhel', Oleg A. Romashko, Tamila P. Heliyon Article The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is suggested. A validity of such approach was verified by the example of studying of extrathermodynamic compensations. Several types of exact linear extrathermodynamic compensations as well as their peculiar type, which peculiarity is indefinable compensation temperature, are established. The criteria that specify these types are stated. These results are illustrated by the identified exact extrathermodynamic compensations in formation of pyrene excimers. Elsevier 2019-06-11 /pmc/articles/PMC6562324/ /pubmed/31211257 http://dx.doi.org/10.1016/j.heliyon.2019.e01839 Text en © 2019 The Authors. Published by Elsevier Ltd. http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Article
Khakhel', Oleg A.
Romashko, Tamila P.
The origin of extrathermodynamic compensations
title The origin of extrathermodynamic compensations
title_full The origin of extrathermodynamic compensations
title_fullStr The origin of extrathermodynamic compensations
title_full_unstemmed The origin of extrathermodynamic compensations
title_short The origin of extrathermodynamic compensations
title_sort origin of extrathermodynamic compensations
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6562324/
https://www.ncbi.nlm.nih.gov/pubmed/31211257
http://dx.doi.org/10.1016/j.heliyon.2019.e01839
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