Active Pore-Edge Engineering of Single-Layer Niobium Diselenide Porous Nanosheets Electrode for Hydrogen Evolution

Two-dimensional transition-metal dichalcogenides (TMDs) possess interesting catalytic properties for the electrochemical-assisted hydrogen-evolution reaction (HER). We used niobium diselenide (NbSe(2)) as a representative TMD, and prepared single-layer NbSe(2) porous nanosheets (PNS) by a double-sonication liquid-phase exfoliation, with H(2)O(2) as a pore-forming agent. The single-layer NbSe(2) PNS were drop-cast on carbon foam (CF) to fabricate a three-dimensional robust NbSe(2) PNS/CF electrode. The NbSe(2) PNS/CF electrode exhibits a high current density of −50 mA cm(−2) with an overpotential of 148 mV and a Tafel slope of 75.8 eV dec(−1) for the HER process. Little deactivation is detected in continuous CV testing up to 20,000 cycles, which suggests that this novel NbSe(2) PNS/CF is a promising catalytic electrode in the HER application. The porous structure of single-layer NbSe(2) nanosheets can enhance the electrochemical performance compared with that of pore-free NbSe(2) nanosheets. These findings illustrate that the single-layer NbSe(2) PNS is a potential electrocatalytic material for HER. More importantly, the electrochemical performance of the NbSe(2) PNS/CF expands the use of two-dimensional TMDs in electrocatalysis-related fields.