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s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols

Mixed s-block metal organometallic reagents have been successfully utilised in the catalytic intramolecular hydroalkoxylation of alkynols. This success has been attributed to the unique manner in which these reagents can overcome the challenges of the reaction: namely OH activation and coordination...

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Detalles Bibliográficos
Autores principales: Fairley, Michael, Davin, Laia, Hernán-Gómez, Alberto, García-Álvarez, Joaquín, O'Hara, Charles T., Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6568277/
https://www.ncbi.nlm.nih.gov/pubmed/31293771
http://dx.doi.org/10.1039/c9sc01598a

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