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Symmetry-guided syntheses of mixed-linker Zr metal–organic frameworks with precise linker locations
While the one-pot reaction of zirconium metal ions with a mixture of two dicarboxylate heterolinkers yielded a 12-c fcu Zr MOF with randomly distributed linkers, the symmetry-guided stepwise reaction produced the same MOF with both linkers precisely located in the framework. In the latter method, li...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6568281/ https://www.ncbi.nlm.nih.gov/pubmed/31293768 http://dx.doi.org/10.1039/c9sc01301f |