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The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites

Layered silicates are suitable for use as fillers in nanocomposites based on their particular features, such as large aspect ratio, easy availability, and chemical resistance. Among them, sericite is distinguished for its higher aspect ratio, higher resilience, and ultraviolet shielding and absorpti...

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Detalles Bibliográficos
Autores principales: Liang, Yu, Yang, Dexin, Yang, Tao, Liang, Ning, Ding, Hao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6571737/
https://www.ncbi.nlm.nih.gov/pubmed/31108885
http://dx.doi.org/10.3390/polym11050900
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author Liang, Yu
Yang, Dexin
Yang, Tao
Liang, Ning
Ding, Hao
author_facet Liang, Yu
Yang, Dexin
Yang, Tao
Liang, Ning
Ding, Hao
author_sort Liang, Yu
collection PubMed
description Layered silicates are suitable for use as fillers in nanocomposites based on their particular features, such as large aspect ratio, easy availability, and chemical resistance. Among them, sericite is distinguished for its higher aspect ratio, higher resilience, and ultraviolet shielding and absorption. Previously, sericite was structure-modified and intercalated by CTAB to expand its interlayer space. The intercalated sericite seems promising for use in the fabrication of polymer/sericite composites or pillared sericite. However, special attention should be paid to the stability of the intercalated sericite because the CTAB inside the layer may be de-intercalated, which would affect the interlayer spacing and its surface properties. In this article, the stability of the sericite intercalated by CTAB was tested by changing different variables, such as different washing solvents, different temperatures, ultrasonic cleaning, and different solution conditions. Finally, sericite/polymer nanocomposites were produced with the stable intercalated sericite, and showed excellent properties compared with pure epoxy resin.
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spelling pubmed-65717372019-06-18 The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites Liang, Yu Yang, Dexin Yang, Tao Liang, Ning Ding, Hao Polymers (Basel) Article Layered silicates are suitable for use as fillers in nanocomposites based on their particular features, such as large aspect ratio, easy availability, and chemical resistance. Among them, sericite is distinguished for its higher aspect ratio, higher resilience, and ultraviolet shielding and absorption. Previously, sericite was structure-modified and intercalated by CTAB to expand its interlayer space. The intercalated sericite seems promising for use in the fabrication of polymer/sericite composites or pillared sericite. However, special attention should be paid to the stability of the intercalated sericite because the CTAB inside the layer may be de-intercalated, which would affect the interlayer spacing and its surface properties. In this article, the stability of the sericite intercalated by CTAB was tested by changing different variables, such as different washing solvents, different temperatures, ultrasonic cleaning, and different solution conditions. Finally, sericite/polymer nanocomposites were produced with the stable intercalated sericite, and showed excellent properties compared with pure epoxy resin. MDPI 2019-05-17 /pmc/articles/PMC6571737/ /pubmed/31108885 http://dx.doi.org/10.3390/polym11050900 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Liang, Yu
Yang, Dexin
Yang, Tao
Liang, Ning
Ding, Hao
The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites
title The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites
title_full The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites
title_fullStr The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites
title_full_unstemmed The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites
title_short The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites
title_sort stability of intercalated sericite by cetyl trimethylammonium ion under different conditions and the preparation of sericite/polymer nanocomposites
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6571737/
https://www.ncbi.nlm.nih.gov/pubmed/31108885
http://dx.doi.org/10.3390/polym11050900
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