Cargando…
The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites
Layered silicates are suitable for use as fillers in nanocomposites based on their particular features, such as large aspect ratio, easy availability, and chemical resistance. Among them, sericite is distinguished for its higher aspect ratio, higher resilience, and ultraviolet shielding and absorpti...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6571737/ https://www.ncbi.nlm.nih.gov/pubmed/31108885 http://dx.doi.org/10.3390/polym11050900 |
_version_ | 1783427478550740992 |
---|---|
author | Liang, Yu Yang, Dexin Yang, Tao Liang, Ning Ding, Hao |
author_facet | Liang, Yu Yang, Dexin Yang, Tao Liang, Ning Ding, Hao |
author_sort | Liang, Yu |
collection | PubMed |
description | Layered silicates are suitable for use as fillers in nanocomposites based on their particular features, such as large aspect ratio, easy availability, and chemical resistance. Among them, sericite is distinguished for its higher aspect ratio, higher resilience, and ultraviolet shielding and absorption. Previously, sericite was structure-modified and intercalated by CTAB to expand its interlayer space. The intercalated sericite seems promising for use in the fabrication of polymer/sericite composites or pillared sericite. However, special attention should be paid to the stability of the intercalated sericite because the CTAB inside the layer may be de-intercalated, which would affect the interlayer spacing and its surface properties. In this article, the stability of the sericite intercalated by CTAB was tested by changing different variables, such as different washing solvents, different temperatures, ultrasonic cleaning, and different solution conditions. Finally, sericite/polymer nanocomposites were produced with the stable intercalated sericite, and showed excellent properties compared with pure epoxy resin. |
format | Online Article Text |
id | pubmed-6571737 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-65717372019-06-18 The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites Liang, Yu Yang, Dexin Yang, Tao Liang, Ning Ding, Hao Polymers (Basel) Article Layered silicates are suitable for use as fillers in nanocomposites based on their particular features, such as large aspect ratio, easy availability, and chemical resistance. Among them, sericite is distinguished for its higher aspect ratio, higher resilience, and ultraviolet shielding and absorption. Previously, sericite was structure-modified and intercalated by CTAB to expand its interlayer space. The intercalated sericite seems promising for use in the fabrication of polymer/sericite composites or pillared sericite. However, special attention should be paid to the stability of the intercalated sericite because the CTAB inside the layer may be de-intercalated, which would affect the interlayer spacing and its surface properties. In this article, the stability of the sericite intercalated by CTAB was tested by changing different variables, such as different washing solvents, different temperatures, ultrasonic cleaning, and different solution conditions. Finally, sericite/polymer nanocomposites were produced with the stable intercalated sericite, and showed excellent properties compared with pure epoxy resin. MDPI 2019-05-17 /pmc/articles/PMC6571737/ /pubmed/31108885 http://dx.doi.org/10.3390/polym11050900 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Liang, Yu Yang, Dexin Yang, Tao Liang, Ning Ding, Hao The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites |
title | The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites |
title_full | The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites |
title_fullStr | The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites |
title_full_unstemmed | The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites |
title_short | The Stability of Intercalated Sericite by Cetyl Trimethylammonium Ion under Different Conditions and the Preparation of Sericite/Polymer Nanocomposites |
title_sort | stability of intercalated sericite by cetyl trimethylammonium ion under different conditions and the preparation of sericite/polymer nanocomposites |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6571737/ https://www.ncbi.nlm.nih.gov/pubmed/31108885 http://dx.doi.org/10.3390/polym11050900 |
work_keys_str_mv | AT liangyu thestabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT yangdexin thestabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT yangtao thestabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT liangning thestabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT dinghao thestabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT liangyu stabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT yangdexin stabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT yangtao stabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT liangning stabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites AT dinghao stabilityofintercalatedsericitebycetyltrimethylammoniumionunderdifferentconditionsandthepreparationofsericitepolymernanocomposites |