The Role of Surfaces in Gas Transport Through Polymer Membranes

This paper describes a procedure to measure the permeability P, diffusivity D, and rate of adsorption k(1), thus determining the solubility S and rate of desorption k(2) of He, N(2), O(2), CH(4), and CO(2) on a polydimethylsiloxane (PDMS) membrane. The described procedure is able to determine experi...

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Detalles Bibliográficos
Autores principales: Firpo, Giuseppe, Angeli, Elena, Guida, Patrizia, Pezzuoli, Denise, Repetto, Diego, Repetto, Luca, Valbusa, Ugo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6572078/
https://www.ncbi.nlm.nih.gov/pubmed/31137564
http://dx.doi.org/10.3390/polym11050910
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author Firpo, Giuseppe
Angeli, Elena
Guida, Patrizia
Pezzuoli, Denise
Repetto, Diego
Repetto, Luca
Valbusa, Ugo
author_facet Firpo, Giuseppe
Angeli, Elena
Guida, Patrizia
Pezzuoli, Denise
Repetto, Diego
Repetto, Luca
Valbusa, Ugo
author_sort Firpo, Giuseppe
collection PubMed
description This paper describes a procedure to measure the permeability P, diffusivity D, and rate of adsorption k(1), thus determining the solubility S and rate of desorption k(2) of He, N(2), O(2), CH(4), and CO(2) on a polydimethylsiloxane (PDMS) membrane. The described procedure is able to determine experimentally all the physical quantities that characterize the gas transport process through a thin rubber polymer membrane. The experiments were carried out at room temperature and at a transmembrane pressure of 1 atm. The results are in good agreement with the available data in the literature and offer an evaluation of k(1) and k(2).
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spelling pubmed-65720782019-06-18 The Role of Surfaces in Gas Transport Through Polymer Membranes Firpo, Giuseppe Angeli, Elena Guida, Patrizia Pezzuoli, Denise Repetto, Diego Repetto, Luca Valbusa, Ugo Polymers (Basel) Article This paper describes a procedure to measure the permeability P, diffusivity D, and rate of adsorption k(1), thus determining the solubility S and rate of desorption k(2) of He, N(2), O(2), CH(4), and CO(2) on a polydimethylsiloxane (PDMS) membrane. The described procedure is able to determine experimentally all the physical quantities that characterize the gas transport process through a thin rubber polymer membrane. The experiments were carried out at room temperature and at a transmembrane pressure of 1 atm. The results are in good agreement with the available data in the literature and offer an evaluation of k(1) and k(2). MDPI 2019-05-20 /pmc/articles/PMC6572078/ /pubmed/31137564 http://dx.doi.org/10.3390/polym11050910 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Firpo, Giuseppe
Angeli, Elena
Guida, Patrizia
Pezzuoli, Denise
Repetto, Diego
Repetto, Luca
Valbusa, Ugo
The Role of Surfaces in Gas Transport Through Polymer Membranes
title The Role of Surfaces in Gas Transport Through Polymer Membranes
title_full The Role of Surfaces in Gas Transport Through Polymer Membranes
title_fullStr The Role of Surfaces in Gas Transport Through Polymer Membranes
title_full_unstemmed The Role of Surfaces in Gas Transport Through Polymer Membranes
title_short The Role of Surfaces in Gas Transport Through Polymer Membranes
title_sort role of surfaces in gas transport through polymer membranes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6572078/
https://www.ncbi.nlm.nih.gov/pubmed/31137564
http://dx.doi.org/10.3390/polym11050910
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