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Rhodium(III)-Catalyzed [4+2] Annulation via C-H Activation: Synthesis of Multi-Substituted Naphthalenone Sulfoxonium Ylides

A convenient Rh(III)-catalyzed C-H activation and cascade [4+2] annulation for the synthesis of naphthalenone sulfoxonium ylides has been developed. This method features perfect regioselectivity, mild and redox-neutral reaction conditions, and broad substrate tolerance with good to excellent yields....

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Detalles Bibliográficos
Autores principales: Song, Xiaohan, Han, Xu, Zhang, Rui, Liu, Hong, Wang, Jiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6572249/
https://www.ncbi.nlm.nih.gov/pubmed/31100874
http://dx.doi.org/10.3390/molecules24101884