Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles

As part of a project aimed at the development of chiral processive catalysts that can write information on a polymer chain we describe the synthesis of two optically active porphyrin macrocycles, which are prepared in 3 steps from an achiral precursor compound. Fluorescence and (1)H‐NMR studies show...

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Detalles Bibliográficos
Autores principales: Varghese, Shaji, Spierenburg, Bram, Bruekers, Jeroen P. J., Swartjes, Anne, White, Paul B., Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6582502/
https://www.ncbi.nlm.nih.gov/pubmed/31244550
http://dx.doi.org/10.1002/ejoc.201900221
Descripción
Sumario:As part of a project aimed at the development of chiral processive catalysts that can write information on a polymer chain we describe the synthesis of two optically active porphyrin macrocycles, which are prepared in 3 steps from an achiral precursor compound. Fluorescence and (1)H‐NMR studies show that one of the macrocycles displays selectivity in the binding of chiral viologen guest molecules.

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