Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles

As part of a project aimed at the development of chiral processive catalysts that can write information on a polymer chain we describe the synthesis of two optically active porphyrin macrocycles, which are prepared in 3 steps from an achiral precursor compound. Fluorescence and (1)H‐NMR studies show...

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Autores principales: Varghese, Shaji, Spierenburg, Bram, Bruekers, Jeroen P. J., Swartjes, Anne, White, Paul B., Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6582502/
https://www.ncbi.nlm.nih.gov/pubmed/31244550
http://dx.doi.org/10.1002/ejoc.201900221
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author Varghese, Shaji
Spierenburg, Bram
Bruekers, Jeroen P. J.
Swartjes, Anne
White, Paul B.
Elemans, Johannes A. A. W.
Nolte, Roeland J. M.
author_facet Varghese, Shaji
Spierenburg, Bram
Bruekers, Jeroen P. J.
Swartjes, Anne
White, Paul B.
Elemans, Johannes A. A. W.
Nolte, Roeland J. M.
author_sort Varghese, Shaji
collection PubMed
description As part of a project aimed at the development of chiral processive catalysts that can write information on a polymer chain we describe the synthesis of two optically active porphyrin macrocycles, which are prepared in 3 steps from an achiral precursor compound. Fluorescence and (1)H‐NMR studies show that one of the macrocycles displays selectivity in the binding of chiral viologen guest molecules.
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spelling pubmed-65825022019-06-24 Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles Varghese, Shaji Spierenburg, Bram Bruekers, Jeroen P. J. Swartjes, Anne White, Paul B. Elemans, Johannes A. A. W. Nolte, Roeland J. M. European J Org Chem Full Papers As part of a project aimed at the development of chiral processive catalysts that can write information on a polymer chain we describe the synthesis of two optically active porphyrin macrocycles, which are prepared in 3 steps from an achiral precursor compound. Fluorescence and (1)H‐NMR studies show that one of the macrocycles displays selectivity in the binding of chiral viologen guest molecules. John Wiley and Sons Inc. 2019-05-03 2019-06-10 /pmc/articles/PMC6582502/ /pubmed/31244550 http://dx.doi.org/10.1002/ejoc.201900221 Text en © 2019 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Full Papers
Varghese, Shaji
Spierenburg, Bram
Bruekers, Jeroen P. J.
Swartjes, Anne
White, Paul B.
Elemans, Johannes A. A. W.
Nolte, Roeland J. M.
Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles
title Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles
title_full Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles
title_fullStr Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles
title_full_unstemmed Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles
title_short Effect of Chirality on the Binding of Viologen Guests in Porphyrin Macrocycles
title_sort effect of chirality on the binding of viologen guests in porphyrin macrocycles
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6582502/
https://www.ncbi.nlm.nih.gov/pubmed/31244550
http://dx.doi.org/10.1002/ejoc.201900221
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