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Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid

The main purpose of this paper was to obtain a material with efficient adsorbing properties and selectivity, to recover the gold (III) from residual diluted solutions resulted from the electroplating process. In this regard, a material was obtained by physico-chemical functionalization of a chemical...

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Autores principales: Mihăilescu, Maria, Negrea, Adina, Ciopec, Mihaela, Davidescu, Corneliu Mircea, Negrea, Petru, Duţeanu, Narcis, Rusu, Gerlinde
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6584572/
https://www.ncbi.nlm.nih.gov/pubmed/31217435
http://dx.doi.org/10.1038/s41598-019-45249-1
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author Mihăilescu, Maria
Negrea, Adina
Ciopec, Mihaela
Davidescu, Corneliu Mircea
Negrea, Petru
Duţeanu, Narcis
Rusu, Gerlinde
author_facet Mihăilescu, Maria
Negrea, Adina
Ciopec, Mihaela
Davidescu, Corneliu Mircea
Negrea, Petru
Duţeanu, Narcis
Rusu, Gerlinde
author_sort Mihăilescu, Maria
collection PubMed
description The main purpose of this paper was to obtain a material with efficient adsorbing properties and selectivity, to recover the gold (III) from residual diluted solutions resulted from the electroplating process. In this regard, a material was obtained by physico-chemical functionalization of a chemically inert support with functional groups of nitrogen and carboxyl. As a source of functional groups glutamic acid was used, and Amberlite XAD7 type acrylic resin was used as solid support. In order to establish the mechanism of the adsorption process, kinetic, thermodynamic and equilibrium studies were performed. The maximum adsorption capacity of the material has been established, and a gold (III) recovery process has been proposed using thermal decomposition of the exhausted adsorbed material. Main objective of this study was to evaluate an environmental friendly adsorbent material to recover gold from secondary industrial sources.
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spelling pubmed-65845722019-06-26 Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid Mihăilescu, Maria Negrea, Adina Ciopec, Mihaela Davidescu, Corneliu Mircea Negrea, Petru Duţeanu, Narcis Rusu, Gerlinde Sci Rep Article The main purpose of this paper was to obtain a material with efficient adsorbing properties and selectivity, to recover the gold (III) from residual diluted solutions resulted from the electroplating process. In this regard, a material was obtained by physico-chemical functionalization of a chemically inert support with functional groups of nitrogen and carboxyl. As a source of functional groups glutamic acid was used, and Amberlite XAD7 type acrylic resin was used as solid support. In order to establish the mechanism of the adsorption process, kinetic, thermodynamic and equilibrium studies were performed. The maximum adsorption capacity of the material has been established, and a gold (III) recovery process has been proposed using thermal decomposition of the exhausted adsorbed material. Main objective of this study was to evaluate an environmental friendly adsorbent material to recover gold from secondary industrial sources. Nature Publishing Group UK 2019-06-19 /pmc/articles/PMC6584572/ /pubmed/31217435 http://dx.doi.org/10.1038/s41598-019-45249-1 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Mihăilescu, Maria
Negrea, Adina
Ciopec, Mihaela
Davidescu, Corneliu Mircea
Negrea, Petru
Duţeanu, Narcis
Rusu, Gerlinde
Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid
title Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid
title_full Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid
title_fullStr Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid
title_full_unstemmed Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid
title_short Gold (III) adsorption from dilute waste solutions onto Amberlite XAD7 resin modified with L-glutamic acid
title_sort gold (iii) adsorption from dilute waste solutions onto amberlite xad7 resin modified with l-glutamic acid
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6584572/
https://www.ncbi.nlm.nih.gov/pubmed/31217435
http://dx.doi.org/10.1038/s41598-019-45249-1
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