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Ionization of gold (γ-methoxy)vinyl complexes generates reactive gold vinyl carbene complexes
Cationic gold vinyl carbene/allylic cation complexes of the form (E)-[(L)AuC(H)C(H)CAr(2)](+) OTf(–) {L = IPr, Ar = Ph [(E)-5a], L = IPr, Ar = 4-C(6)H(4)OMe [(E)-5b], L = P(t-Bu)(2)o-biphenyl, Ar = 4-C(6)H(4)OMe [(E)-5c]} were generated in solution via Lewis acid-mediated ionization of the correspon...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6585879/ https://www.ncbi.nlm.nih.gov/pubmed/31360421 http://dx.doi.org/10.1039/c9sc01574d |