A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol

For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long‐term stability was demonstra...

Descripción completa

Detalles Bibliográficos
Autores principales: Andérez‐Fernández, María, Vogt, Lydia K., Fischer, Steffen, Zhou, Wei, Jiao, Haijun, Garbe, Marcel, Elangovan, Saravanakumar, Junge, Kathrin, Junge, Henrik, Ludwig, Ralf, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6586016/
https://www.ncbi.nlm.nih.gov/pubmed/27910197
http://dx.doi.org/10.1002/anie.201610182
_version_ 1783428821120188416
author Andérez‐Fernández, María
Vogt, Lydia K.
Fischer, Steffen
Zhou, Wei
Jiao, Haijun
Garbe, Marcel
Elangovan, Saravanakumar
Junge, Kathrin
Junge, Henrik
Ludwig, Ralf
Beller, Matthias
author_facet Andérez‐Fernández, María
Vogt, Lydia K.
Fischer, Steffen
Zhou, Wei
Jiao, Haijun
Garbe, Marcel
Elangovan, Saravanakumar
Junge, Kathrin
Junge, Henrik
Ludwig, Ralf
Beller, Matthias
author_sort Andérez‐Fernández, María
collection PubMed
description For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long‐term stability was demonstrated for the Mn‐PNPiPr catalyst, as a turnover of more than 20 000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated.
format Online
Article
Text
id pubmed-6586016
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-65860162019-06-27 A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol Andérez‐Fernández, María Vogt, Lydia K. Fischer, Steffen Zhou, Wei Jiao, Haijun Garbe, Marcel Elangovan, Saravanakumar Junge, Kathrin Junge, Henrik Ludwig, Ralf Beller, Matthias Angew Chem Int Ed Engl Communications For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long‐term stability was demonstrated for the Mn‐PNPiPr catalyst, as a turnover of more than 20 000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated. John Wiley and Sons Inc. 2016-12-02 2017-01-09 /pmc/articles/PMC6586016/ /pubmed/27910197 http://dx.doi.org/10.1002/anie.201610182 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Andérez‐Fernández, María
Vogt, Lydia K.
Fischer, Steffen
Zhou, Wei
Jiao, Haijun
Garbe, Marcel
Elangovan, Saravanakumar
Junge, Kathrin
Junge, Henrik
Ludwig, Ralf
Beller, Matthias
A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
title A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
title_full A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
title_fullStr A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
title_full_unstemmed A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
title_short A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
title_sort stable manganese pincer catalyst for the selective dehydrogenation of methanol
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6586016/
https://www.ncbi.nlm.nih.gov/pubmed/27910197
http://dx.doi.org/10.1002/anie.201610182
work_keys_str_mv AT anderezfernandezmaria astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT vogtlydiak astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT fischersteffen astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT zhouwei astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT jiaohaijun astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT garbemarcel astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT elangovansaravanakumar astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT jungekathrin astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT jungehenrik astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT ludwigralf astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT bellermatthias astablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT anderezfernandezmaria stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT vogtlydiak stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT fischersteffen stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT zhouwei stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT jiaohaijun stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT garbemarcel stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT elangovansaravanakumar stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT jungekathrin stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT jungehenrik stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT ludwigralf stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol
AT bellermatthias stablemanganesepincercatalystfortheselectivedehydrogenationofmethanol

Ejemplares similares