Non‐Porous versus Mesoporous Siliceous Materials for CO(2) Capture

In this study, the adsorption properties of a Stöber silica‐based material towards CO(2) were evaluated for the first time. The use of Stöber silica as support is interesting for real technological applications mainly due to economic factors. Furthermore, a direct comparison between the non porous Stöber sample with an ordered porous material (based on MCM‐41 silica) allowed to evaluate the effect of the porosity on the CO(2) adsorption properties. In order to make silica materials reactive towards CO(2), they were functionalized by introducing amino groups via grafting of 3‐[2‐(2‐aminoethyl)aminoethyl]aminopropyltrimethoxysilane. After a qualitative study of the CO(2) adsorption, the quantitative determination of CO(2) adsorption capacity at 35 °C revealed that the mesoporous material is more efficient compared to the Stöber‐based one (adsorption capacity values of 0.49 and 0.58 mol/kg for Stöber‐based and mesoporous samples). However, since the difference in the adsorption capacity is only about 15 % and the Stöber‐based sample is considerably cheaper, the non‐porous sample should be considered as a favourable adsorbent material for CO(2) capture applications.