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Weak Pnictogen Bond with Bismuth: Experimental Evidence Based on Bi−P Through‐Space Coupling

To study pnictogen bonding involving bismuth, flexible accordion‐like molecular complexes of the composition [P(C(6)H(4)‐o‐CH(2)SCH(3))(3)BiX(3)], (X=Cl, Br, I) have been synthesised and characterised. The strength of the weak and mainly electrostatic interaction between the Bi and P centres strongl...

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Detalles Bibliográficos
Autores principales:	Mokrai, Réka, Barrett, Jamie, Apperley, David C., Batsanov, Andrei S., Benkő, Zoltán, Heift, Dominikus
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6593703/ https://www.ncbi.nlm.nih.gov/pubmed/30680824 http://dx.doi.org/10.1002/chem.201900266

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