Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex

The long‐sought carbene–bismuthinidene, (CAAC)Bi(Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent bismuth complex and the extension of the carbene‐pnictinidene concept to a non‐toxic metallic element (Bi). The bonding has been investigated...

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Detalles Bibliográficos
Autores principales: Wang, Guocang, Freeman, Lucas A., Dickie, Diane A., Mokrai, Réka, Benkő, Zoltán, Gilliard, Robert J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6593863/
https://www.ncbi.nlm.nih.gov/pubmed/30706565
http://dx.doi.org/10.1002/chem.201900458
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author Wang, Guocang
Freeman, Lucas A.
Dickie, Diane A.
Mokrai, Réka
Benkő, Zoltán
Gilliard, Robert J.
author_facet Wang, Guocang
Freeman, Lucas A.
Dickie, Diane A.
Mokrai, Réka
Benkő, Zoltán
Gilliard, Robert J.
author_sort Wang, Guocang
collection PubMed
description The long‐sought carbene–bismuthinidene, (CAAC)Bi(Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent bismuth complex and the extension of the carbene‐pnictinidene concept to a non‐toxic metallic element (Bi). The bonding has been investigated by single‐crystal X‐ray diffraction studies and DFT calculations. This report also highlights the hitherto unknown reducing and ligand transfer capability of a beryllium(0) complex.
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spelling pubmed-65938632019-07-10 Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex Wang, Guocang Freeman, Lucas A. Dickie, Diane A. Mokrai, Réka Benkő, Zoltán Gilliard, Robert J. Chemistry Communications The long‐sought carbene–bismuthinidene, (CAAC)Bi(Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent bismuth complex and the extension of the carbene‐pnictinidene concept to a non‐toxic metallic element (Bi). The bonding has been investigated by single‐crystal X‐ray diffraction studies and DFT calculations. This report also highlights the hitherto unknown reducing and ligand transfer capability of a beryllium(0) complex. John Wiley and Sons Inc. 2019-02-27 2019-03-21 /pmc/articles/PMC6593863/ /pubmed/30706565 http://dx.doi.org/10.1002/chem.201900458 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Wang, Guocang
Freeman, Lucas A.
Dickie, Diane A.
Mokrai, Réka
Benkő, Zoltán
Gilliard, Robert J.
Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
title Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
title_full Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
title_fullStr Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
title_full_unstemmed Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
title_short Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
title_sort isolation of cyclic(alkyl)(amino) carbene–bismuthinidene mediated by a beryllium(0) complex
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6593863/
https://www.ncbi.nlm.nih.gov/pubmed/30706565
http://dx.doi.org/10.1002/chem.201900458
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