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Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex

The long‐sought carbene–bismuthinidene, (CAAC)Bi(Ph), has been synthesized. Notably, this represents both the first example of a carbene‐stabilized subvalent bismuth complex and the extension of the carbene‐pnictinidene concept to a non‐toxic metallic element (Bi). The bonding has been investigated...

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Detalles Bibliográficos
Autores principales: Wang, Guocang, Freeman, Lucas A., Dickie, Diane A., Mokrai, Réka, Benkő, Zoltán, Gilliard, Robert J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6593863/
https://www.ncbi.nlm.nih.gov/pubmed/30706565
http://dx.doi.org/10.1002/chem.201900458