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Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems

This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii)...

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Autores principales: Esperança, José M. S. S., Tariq, Mohammad, Pereiro, Ana B., Araújo, João M. M., Seddon, Kenneth R., Rebelo, Luis Paulo N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6596442/
https://www.ncbi.nlm.nih.gov/pubmed/31281812
http://dx.doi.org/10.3389/fchem.2019.00450
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author Esperança, José M. S. S.
Tariq, Mohammad
Pereiro, Ana B.
Araújo, João M. M.
Seddon, Kenneth R.
Rebelo, Luis Paulo N.
author_facet Esperança, José M. S. S.
Tariq, Mohammad
Pereiro, Ana B.
Araújo, João M. M.
Seddon, Kenneth R.
Rebelo, Luis Paulo N.
author_sort Esperança, José M. S. S.
collection PubMed
description This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of C(p)/V(m) at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems.
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spelling pubmed-65964422019-07-05 Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems Esperança, José M. S. S. Tariq, Mohammad Pereiro, Ana B. Araújo, João M. M. Seddon, Kenneth R. Rebelo, Luis Paulo N. Front Chem Chemistry This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of C(p)/V(m) at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems. Frontiers Media S.A. 2019-06-20 /pmc/articles/PMC6596442/ /pubmed/31281812 http://dx.doi.org/10.3389/fchem.2019.00450 Text en Copyright © 2019 Esperança, Tariq, Pereiro, Araújo, Seddon and Rebelo. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Esperança, José M. S. S.
Tariq, Mohammad
Pereiro, Ana B.
Araújo, João M. M.
Seddon, Kenneth R.
Rebelo, Luis Paulo N.
Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
title Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
title_full Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
title_fullStr Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
title_full_unstemmed Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
title_short Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
title_sort anomalous and not-so-common behavior in common ionic liquids and ionic liquid-containing systems
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6596442/
https://www.ncbi.nlm.nih.gov/pubmed/31281812
http://dx.doi.org/10.3389/fchem.2019.00450
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