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Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems
This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii)...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6596442/ https://www.ncbi.nlm.nih.gov/pubmed/31281812 http://dx.doi.org/10.3389/fchem.2019.00450 |
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author | Esperança, José M. S. S. Tariq, Mohammad Pereiro, Ana B. Araújo, João M. M. Seddon, Kenneth R. Rebelo, Luis Paulo N. |
author_facet | Esperança, José M. S. S. Tariq, Mohammad Pereiro, Ana B. Araújo, João M. M. Seddon, Kenneth R. Rebelo, Luis Paulo N. |
author_sort | Esperança, José M. S. S. |
collection | PubMed |
description | This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of C(p)/V(m) at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems. |
format | Online Article Text |
id | pubmed-6596442 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-65964422019-07-05 Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems Esperança, José M. S. S. Tariq, Mohammad Pereiro, Ana B. Araújo, João M. M. Seddon, Kenneth R. Rebelo, Luis Paulo N. Front Chem Chemistry This work highlights unexpected, not so well known responses of ionic liquids and ionic liquid-containing systems, which are reported in a collective manner, as a short review. Examples include: (i) Minima in the temperature dependence of the isobaric thermal expansion coefficient of some ILs; (ii) Viscosity Minima in binary mixtures of IL + Molecular solvents; (iii) Anomalies in the surface tension within a family of ILs; (iv) The constancy among IL substitution of C(p)/V(m) at and around room temperature; (v) ILs as glass forming liquids; (vi) Alternate odd-even side alkyl chain length effects; (vii) Absolute negative pressures in ILs and IL-containing systems; (viii) Reversed-charged ionic liquid pairs; (ix) LCST immiscibility behavior in IL + solvent systems. Frontiers Media S.A. 2019-06-20 /pmc/articles/PMC6596442/ /pubmed/31281812 http://dx.doi.org/10.3389/fchem.2019.00450 Text en Copyright © 2019 Esperança, Tariq, Pereiro, Araújo, Seddon and Rebelo. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Esperança, José M. S. S. Tariq, Mohammad Pereiro, Ana B. Araújo, João M. M. Seddon, Kenneth R. Rebelo, Luis Paulo N. Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
title | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
title_full | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
title_fullStr | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
title_full_unstemmed | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
title_short | Anomalous and Not-So-Common Behavior in Common Ionic Liquids and Ionic Liquid-Containing Systems |
title_sort | anomalous and not-so-common behavior in common ionic liquids and ionic liquid-containing systems |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6596442/ https://www.ncbi.nlm.nih.gov/pubmed/31281812 http://dx.doi.org/10.3389/fchem.2019.00450 |
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