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Brønsted Acid Scaling Relationships Enable Control Over Product Selectivity from O(2) Reduction with a Mononuclear Cobalt Porphyrin Catalyst

[Image: see text] The selective reduction of O(2), typically with the goal of forming H(2)O, represents a long-standing challenge in the field of catalysis. Macrocyclic transition-metal complexes, and cobalt porphyrins in particular, have been the focus of extensive study as catalysts for this react...

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Detalles Bibliográficos
Autores principales: Wang, Yu-Heng, Schneider, Patrick E., Goldsmith, Zachary K., Mondal, Biswajit, Hammes-Schiffer, Sharon, Stahl, Shannon S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6598176/
https://www.ncbi.nlm.nih.gov/pubmed/31263762
http://dx.doi.org/10.1021/acscentsci.9b00194