A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids

A Ru(ii)-catalyzed direct access to various functionalized allenoic acids via C–H allenylation of readily available aryl carboxylic acids with propargylic acetates is reported. Axially chiral allenoic acids could be obtained in high ee by using optically active propargylic acetates through a chirali...

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Detalles Bibliográficos
Autores principales: Wu, Xiaoyan, Fan, Junjie, Fu, Chunling, Ma, Shengming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6598647/
https://www.ncbi.nlm.nih.gov/pubmed/31341585
http://dx.doi.org/10.1039/c9sc00603f
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author Wu, Xiaoyan
Fan, Junjie
Fu, Chunling
Ma, Shengming
author_facet Wu, Xiaoyan
Fan, Junjie
Fu, Chunling
Ma, Shengming
author_sort Wu, Xiaoyan
collection PubMed
description A Ru(ii)-catalyzed direct access to various functionalized allenoic acids via C–H allenylation of readily available aryl carboxylic acids with propargylic acetates is reported. Axially chiral allenoic acids could be obtained in high ee by using optically active propargylic acetates through a chirality transfer strategy.
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spelling pubmed-65986472019-07-24 A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids Wu, Xiaoyan Fan, Junjie Fu, Chunling Ma, Shengming Chem Sci Chemistry A Ru(ii)-catalyzed direct access to various functionalized allenoic acids via C–H allenylation of readily available aryl carboxylic acids with propargylic acetates is reported. Axially chiral allenoic acids could be obtained in high ee by using optically active propargylic acetates through a chirality transfer strategy. Royal Society of Chemistry 2019-05-10 /pmc/articles/PMC6598647/ /pubmed/31341585 http://dx.doi.org/10.1039/c9sc00603f Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Wu, Xiaoyan
Fan, Junjie
Fu, Chunling
Ma, Shengming
A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids
title A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids
title_full A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids
title_fullStr A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids
title_full_unstemmed A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids
title_short A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids
title_sort ruthenium(ii)-catalyzed c–h allenylation-based approach to allenoic acids
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6598647/
https://www.ncbi.nlm.nih.gov/pubmed/31341585
http://dx.doi.org/10.1039/c9sc00603f
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