Polyoxometalate-Based Catalysts for CO(2) Conversion

Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of reactions. In this focused review, the applications...

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Detalles Bibliográficos
Autores principales: Cao, Yanwei, Chen, Qiongyao, Shen, Chaoren, He, Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6600423/
https://www.ncbi.nlm.nih.gov/pubmed/31151282
http://dx.doi.org/10.3390/molecules24112069
Descripción
Sumario:Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of reactions. In this focused review, the applications of POMs as promising catalysts or co-catalysts for CO(2) conversion, including CO(2) photo/electro reduction and CO(2) as a carbonyl source for the carbonylation process are summarized. A brief perspective on the potentiality in this field is proposed.

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