Cargando…

Polyoxometalate-Based Catalysts for CO(2) Conversion

Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of reactions. In this focused review, the applications...

Descripción completa

Detalles Bibliográficos
Autores principales: Cao, Yanwei, Chen, Qiongyao, Shen, Chaoren, He, Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6600423/
https://www.ncbi.nlm.nih.gov/pubmed/31151282
http://dx.doi.org/10.3390/molecules24112069
_version_ 1783431112808202240
author Cao, Yanwei
Chen, Qiongyao
Shen, Chaoren
He, Lin
author_facet Cao, Yanwei
Chen, Qiongyao
Shen, Chaoren
He, Lin
author_sort Cao, Yanwei
collection PubMed
description Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of reactions. In this focused review, the applications of POMs as promising catalysts or co-catalysts for CO(2) conversion, including CO(2) photo/electro reduction and CO(2) as a carbonyl source for the carbonylation process are summarized. A brief perspective on the potentiality in this field is proposed.
format Online
Article
Text
id pubmed-6600423
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-66004232019-07-16 Polyoxometalate-Based Catalysts for CO(2) Conversion Cao, Yanwei Chen, Qiongyao Shen, Chaoren He, Lin Molecules Review Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of reactions. In this focused review, the applications of POMs as promising catalysts or co-catalysts for CO(2) conversion, including CO(2) photo/electro reduction and CO(2) as a carbonyl source for the carbonylation process are summarized. A brief perspective on the potentiality in this field is proposed. MDPI 2019-05-30 /pmc/articles/PMC6600423/ /pubmed/31151282 http://dx.doi.org/10.3390/molecules24112069 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Cao, Yanwei
Chen, Qiongyao
Shen, Chaoren
He, Lin
Polyoxometalate-Based Catalysts for CO(2) Conversion
title Polyoxometalate-Based Catalysts for CO(2) Conversion
title_full Polyoxometalate-Based Catalysts for CO(2) Conversion
title_fullStr Polyoxometalate-Based Catalysts for CO(2) Conversion
title_full_unstemmed Polyoxometalate-Based Catalysts for CO(2) Conversion
title_short Polyoxometalate-Based Catalysts for CO(2) Conversion
title_sort polyoxometalate-based catalysts for co(2) conversion
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6600423/
https://www.ncbi.nlm.nih.gov/pubmed/31151282
http://dx.doi.org/10.3390/molecules24112069
work_keys_str_mv AT caoyanwei polyoxometalatebasedcatalystsforco2conversion
AT chenqiongyao polyoxometalatebasedcatalystsforco2conversion
AT shenchaoren polyoxometalatebasedcatalystsforco2conversion
AT helin polyoxometalatebasedcatalystsforco2conversion