Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions

Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-d(8) or in THF-d(8)/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic s...

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Autores principales: Amin, Hawraz I. M., Raviola, Carlotta, Amin, Ahmed A., Mannucci, Barbara, Protti, Stefano, Fagnoni, Maurizio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6601019/
https://www.ncbi.nlm.nih.gov/pubmed/31181774
http://dx.doi.org/10.3390/molecules24112164
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author Amin, Hawraz I. M.
Raviola, Carlotta
Amin, Ahmed A.
Mannucci, Barbara
Protti, Stefano
Fagnoni, Maurizio
author_facet Amin, Hawraz I. M.
Raviola, Carlotta
Amin, Ahmed A.
Mannucci, Barbara
Protti, Stefano
Fagnoni, Maurizio
author_sort Amin, Hawraz I. M.
collection PubMed
description Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-d(8) or in THF-d(8)/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents.
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spelling pubmed-66010192019-07-18 Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions Amin, Hawraz I. M. Raviola, Carlotta Amin, Ahmed A. Mannucci, Barbara Protti, Stefano Fagnoni, Maurizio Molecules Article Hydrodeaminated and monodeuterated aromatics were obtained via a visible-light driven reaction of arylazo sulfones. Deuteration occurs efficiently in deuterated media such as isopropanol-d(8) or in THF-d(8)/water mixtures and exhibits a high tolerance to the nature and the position of the aromatic substituents. MDPI 2019-06-08 /pmc/articles/PMC6601019/ /pubmed/31181774 http://dx.doi.org/10.3390/molecules24112164 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Amin, Hawraz I. M.
Raviola, Carlotta
Amin, Ahmed A.
Mannucci, Barbara
Protti, Stefano
Fagnoni, Maurizio
Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions
title Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions
title_full Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions
title_fullStr Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions
title_full_unstemmed Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions
title_short Hydro/Deutero Deamination of Arylazo Sulfones under Metal- and (Photo)Catalyst-Free Conditions
title_sort hydro/deutero deamination of arylazo sulfones under metal- and (photo)catalyst-free conditions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6601019/
https://www.ncbi.nlm.nih.gov/pubmed/31181774
http://dx.doi.org/10.3390/molecules24112164
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