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Robust perfluorophenylboronic acid-catalyzed stereoselective synthesis of 2,3-unsaturated O-, C-, N- and S-linked glycosides

A convenient protocol was developed for the synthesis of 2,3-unsaturated C-, O-, N- and S-linked glycosides (enosides) using 20 mol % perflurophenylboronic acid catalyst via Ferrier rearrangement. Using this protocol, D-glucals and L-rhamnals reacted with various C-, O-, N- and S-nucleophiles to giv...

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Detalles Bibliográficos
Autores principales: Tatina, Madhu Babu, Mengxin, Xia, Peilin, Rao, Judeh, Zaher M A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604698/
https://www.ncbi.nlm.nih.gov/pubmed/31293675
http://dx.doi.org/10.3762/bjoc.15.125

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