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Insertion of [1.1.1]propellane into aromatic disulfides

Herein we present the synthesis of symmetrically and unsymmetrically substituted 1,3-bissulfanylbicyclo[1.1.1]pentanes from disulfides and [1.1.1]propellane. Bicyclo[1.1.1]pentanes (BCPs) recently gained interest as rigid linkers and as bioisosters of para-substituted benzene and alkyne moieties. Th...

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Detalles Bibliográficos
Autores principales:	Bär, Robin M, Heinrich, Gregor, Nieger, Martin, Fuhr, Olaf, Bräse, Stefan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2019
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604700/ https://www.ncbi.nlm.nih.gov/pubmed/31293664 http://dx.doi.org/10.3762/bjoc.15.114

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