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Understanding the unexpected effect of frequency on the kinetics of a covalent reaction under ball-milling conditions
We here explore how ball-mill-grinding frequency affects the kinetics of a disulfide exchange reaction. Our kinetic data show that the reaction progress is similar at all the frequencies studied (15–30 Hz), including a significant induction time before the nucleation and growth process starts. This...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604707/ https://www.ncbi.nlm.nih.gov/pubmed/31293670 http://dx.doi.org/10.3762/bjoc.15.120 |