Self-assembly behaviors of perylene- and naphthalene-crown macrocycle conjugates in aqueous medium

The synthesis of conjugates of perylene diimide (PDI) and naphthalene diimide (NDI) modified with two benzo-21-crown-7 ethers (B21C7) are herein described. Their self-assembly behavior in various solvents was investigated particularly in aqueous medium, due to the recently discovered hydrophilic pro...

Descripción completa

Detalles Bibliográficos
Autores principales: Shen, Xin, Li, Bo, Pan, Tiezheng, Wu, Jianfeng, Wang, Yangxin, Shang, Jie, Ge, Yan, Jin, Lin, Qi, Zhenhui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604709/
https://www.ncbi.nlm.nih.gov/pubmed/31293667
http://dx.doi.org/10.3762/bjoc.15.117
Descripción
Sumario:The synthesis of conjugates of perylene diimide (PDI) and naphthalene diimide (NDI) modified with two benzo-21-crown-7 ethers (B21C7) are herein described. Their self-assembly behavior in various solvents was investigated particularly in aqueous medium, due to the recently discovered hydrophilic properties of B21C7 crown macrocycle. An unexpected fluorescence quenching phenomenon was observed in the PDI-B21C7 macrocycle conjugate in chloroform. The detailed UV–vis absorption and fluorescence spectra of these PDI/NDI derivatives in different solvents as well as their morphologies were investigated.

Ejemplares similares