Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane

The severely ozone‐depleting trichlorofluoromethane is still appearing in several recycling processes or industrial applications. A simple and selective supramolecular complex formation of per‐methylated α‐cyclodextrin (1) with the highly volatile trichlorofluoromethane (2) is reported. This interac...

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Detalles Bibliográficos
Autores principales: Ryvlin, Dimitrij, Girschikofsky, Maiko, Schollmeyer, Dieter, Hellmann, Ralf, Waldvogel, Siegfried R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6607158/
https://www.ncbi.nlm.nih.gov/pubmed/31565344
http://dx.doi.org/10.1002/gch2.201800057
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author Ryvlin, Dimitrij
Girschikofsky, Maiko
Schollmeyer, Dieter
Hellmann, Ralf
Waldvogel, Siegfried R.
author_facet Ryvlin, Dimitrij
Girschikofsky, Maiko
Schollmeyer, Dieter
Hellmann, Ralf
Waldvogel, Siegfried R.
author_sort Ryvlin, Dimitrij
collection PubMed
description The severely ozone‐depleting trichlorofluoromethane is still appearing in several recycling processes or industrial applications. A simple and selective supramolecular complex formation of per‐methylated α‐cyclodextrin (1) with the highly volatile trichlorofluoromethane (2) is reported. This interaction moreover leads to thermally stable crystals. Per‐methylated α‐cyclodextrin is successfully exploited as a reversible and selective adsorption material for liquid and airborne trichlorofluoromethane as well as an affinity material for the chemical sensing and detection of this particular volatile organic component.
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spelling pubmed-66071582019-09-27 Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane Ryvlin, Dimitrij Girschikofsky, Maiko Schollmeyer, Dieter Hellmann, Ralf Waldvogel, Siegfried R. Glob Chall Communications The severely ozone‐depleting trichlorofluoromethane is still appearing in several recycling processes or industrial applications. A simple and selective supramolecular complex formation of per‐methylated α‐cyclodextrin (1) with the highly volatile trichlorofluoromethane (2) is reported. This interaction moreover leads to thermally stable crystals. Per‐methylated α‐cyclodextrin is successfully exploited as a reversible and selective adsorption material for liquid and airborne trichlorofluoromethane as well as an affinity material for the chemical sensing and detection of this particular volatile organic component. John Wiley and Sons Inc. 2018-08-12 /pmc/articles/PMC6607158/ /pubmed/31565344 http://dx.doi.org/10.1002/gch2.201800057 Text en © 2018 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Ryvlin, Dimitrij
Girschikofsky, Maiko
Schollmeyer, Dieter
Hellmann, Ralf
Waldvogel, Siegfried R.
Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane
title Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane
title_full Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane
title_fullStr Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane
title_full_unstemmed Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane
title_short Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane
title_sort methyl‐substituted α‐cyclodextrin as affinity material for storage, separation, and detection of trichlorofluoromethane
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6607158/
https://www.ncbi.nlm.nih.gov/pubmed/31565344
http://dx.doi.org/10.1002/gch2.201800057
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