High‐Efficiency Direct Ammonia Fuel Cells Based on BaZr(0.1)Ce(0.7)Y(0.2)O(3−) (δ)/Pd Oxide‐Metal Junctions

A direct ammonia‐type intermediate temperature fuel cell is examined by means of a hydrogen membrane fuel cell (HMFC) comprising 1‐µm‐thick BaZr(0.1)Ce(0.7)Y(0.2)O(3−) (δ) (BZCY) thin‐film electrolyte and Pd solid anode. It generates the maximum power density of 0.58 W cm(−2) at 600 °C with ammonia fuels, and this value is found to be three times larger than the champion data of the recently reported direct ammonia‐type proton‐conducting ceramic fuel cells (PCFCs). AC impedance spectroscopy is performed to determine the interfacial polarization resistances, disclosing that the anodic overpotentials of HMFCs are at least one order of magnitude smaller than those of anode‐supported PCFC under relatively high DC outputs. The anode reactions are driven by the oxidation of monoatomic hydrogen dissolving at the BZCY/Pd solid–solid interface, mediated via proton transfer from Pd to BZCY. The electrochemical analysis reveals that the BZCY/Pd junction forms Ohmic contact without growth of wide depletion layer and thus facilitates the proton transfer reactions because the interfacial region beneath Pd electrode can accommodate amounts of protonic defects as well as the bulk of BZCY due to the small depletion of holes under hole–proton thermodynamic equilibrium.