Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates

The use of carbon dioxide (CO(2)) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO(2) are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of org...

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Detalles Bibliográficos
Autores principales: Fujihara, Tetsuaki, Tsuji, Yasushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6610474/
https://www.ncbi.nlm.nih.gov/pubmed/31316967
http://dx.doi.org/10.3389/fchem.2019.00430
Descripción
Sumario:The use of carbon dioxide (CO(2)) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO(2) are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of organic substrates with CO(2) via allyl metal intermediates. First, carboxylation reactions via transmetalation are reviewed. Second, catalytic carboxylation reactions using allyl electrophiles and suitable reducing agents are summarized. The last section discusses the catalytic carboxylation reactions via addition reactions, affording allyl metal intermediates.

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