Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates

The use of carbon dioxide (CO(2)) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO(2) are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of org...

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Autores principales: Fujihara, Tetsuaki, Tsuji, Yasushi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6610474/
https://www.ncbi.nlm.nih.gov/pubmed/31316967
http://dx.doi.org/10.3389/fchem.2019.00430
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author Fujihara, Tetsuaki
Tsuji, Yasushi
author_facet Fujihara, Tetsuaki
Tsuji, Yasushi
author_sort Fujihara, Tetsuaki
collection PubMed
description The use of carbon dioxide (CO(2)) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO(2) are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of organic substrates with CO(2) via allyl metal intermediates. First, carboxylation reactions via transmetalation are reviewed. Second, catalytic carboxylation reactions using allyl electrophiles and suitable reducing agents are summarized. The last section discusses the catalytic carboxylation reactions via addition reactions, affording allyl metal intermediates.
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spelling pubmed-66104742019-07-17 Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates Fujihara, Tetsuaki Tsuji, Yasushi Front Chem Chemistry The use of carbon dioxide (CO(2)) is an important issue with regard to current climate research and the Earth's environment. Transition metal-catalyzed carboxylation reactions using CO(2) are highly attractive. This review summarizes the transition metal-catalyzed carboxylation reactions of organic substrates with CO(2) via allyl metal intermediates. First, carboxylation reactions via transmetalation are reviewed. Second, catalytic carboxylation reactions using allyl electrophiles and suitable reducing agents are summarized. The last section discusses the catalytic carboxylation reactions via addition reactions, affording allyl metal intermediates. Frontiers Media S.A. 2019-06-27 /pmc/articles/PMC6610474/ /pubmed/31316967 http://dx.doi.org/10.3389/fchem.2019.00430 Text en Copyright © 2019 Fujihara and Tsuji. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Fujihara, Tetsuaki
Tsuji, Yasushi
Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates
title Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates
title_full Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates
title_fullStr Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates
title_full_unstemmed Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates
title_short Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates
title_sort carboxylation reactions using carbon dioxide as the c1 source via catalytically generated allyl metal intermediates
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6610474/
https://www.ncbi.nlm.nih.gov/pubmed/31316967
http://dx.doi.org/10.3389/fchem.2019.00430
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AT tsujiyasushi carboxylationreactionsusingcarbondioxideasthec1sourceviacatalyticallygeneratedallylmetalintermediates

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