A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates

Herein a highly active non-precious transition metal catalyst system for homogeneous hydrogenation of carbon dioxide to formate is presented. The application of selected nickel(ii) salts in combination with tailored multidentate ligands enabled the effective transformation of carbon dioxide with an...

Descripción completa

Detalles Bibliográficos
Autores principales: Schieweck, Benjamin G., Westhues, Niklas F., Klankermayer, Jürgen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6611062/
https://www.ncbi.nlm.nih.gov/pubmed/31341604
http://dx.doi.org/10.1039/c8sc05230a
_version_ 1783432623651028992
author Schieweck, Benjamin G.
Westhues, Niklas F.
Klankermayer, Jürgen
author_facet Schieweck, Benjamin G.
Westhues, Niklas F.
Klankermayer, Jürgen
author_sort Schieweck, Benjamin G.
collection PubMed
description Herein a highly active non-precious transition metal catalyst system for homogeneous hydrogenation of carbon dioxide to formate is presented. The application of selected nickel(ii) salts in combination with tailored multidentate ligands enabled the effective transformation of carbon dioxide with an exceptional TON of up to 4.65 × 10(6). This unprecedented productivity based on the novel nickel catalyst not only outmatches that of existing systems containing first row transition metals, but also established catalysts based on precious transition metals.
format Online
Article
Text
id pubmed-6611062
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-66110622019-07-24 A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates Schieweck, Benjamin G. Westhues, Niklas F. Klankermayer, Jürgen Chem Sci Chemistry Herein a highly active non-precious transition metal catalyst system for homogeneous hydrogenation of carbon dioxide to formate is presented. The application of selected nickel(ii) salts in combination with tailored multidentate ligands enabled the effective transformation of carbon dioxide with an exceptional TON of up to 4.65 × 10(6). This unprecedented productivity based on the novel nickel catalyst not only outmatches that of existing systems containing first row transition metals, but also established catalysts based on precious transition metals. Royal Society of Chemistry 2019-05-31 /pmc/articles/PMC6611062/ /pubmed/31341604 http://dx.doi.org/10.1039/c8sc05230a Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Schieweck, Benjamin G.
Westhues, Niklas F.
Klankermayer, Jürgen
A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
title A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
title_full A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
title_fullStr A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
title_full_unstemmed A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
title_short A highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
title_sort highly active non-precious transition metal catalyst for the hydrogenation of carbon dioxide to formates
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6611062/
https://www.ncbi.nlm.nih.gov/pubmed/31341604
http://dx.doi.org/10.1039/c8sc05230a
work_keys_str_mv AT schieweckbenjaming ahighlyactivenonprecioustransitionmetalcatalystforthehydrogenationofcarbondioxidetoformates
AT westhuesniklasf ahighlyactivenonprecioustransitionmetalcatalystforthehydrogenationofcarbondioxidetoformates
AT klankermayerjurgen ahighlyactivenonprecioustransitionmetalcatalystforthehydrogenationofcarbondioxidetoformates
AT schieweckbenjaming highlyactivenonprecioustransitionmetalcatalystforthehydrogenationofcarbondioxidetoformates
AT westhuesniklasf highlyactivenonprecioustransitionmetalcatalystforthehydrogenationofcarbondioxidetoformates
AT klankermayerjurgen highlyactivenonprecioustransitionmetalcatalystforthehydrogenationofcarbondioxidetoformates

Ejemplares similares