Preparation of Attapulgite/CoFe(2)O(4) Magnetic Composites for Efficient Adsorption of Tannic Acid from Aqueous Solution

The use of attapulgite (ATP)-based materials for adsorption of pollutants from water and wastewater has received growing attention. However, recovering ATP-based adsorbents remains a challenge. In this study, a magnetic adsorbent ATP/CoFe(2)O(4) with high tannic acid (TA) adsorptive capacity was fabricated via a facile co-precipitation approach and was well characterized. The loaded CoFe(2)O(4) particles were embedded into the adsorbent surfaces to allow magnetic separability. For this material, its TA adsorption kinetics, isotherm behavior, and magnetic separation efficiency are reported. The developed magnetic composites had rapid sorption kinetics of 3 h, high sorption capacity of 109.36 mg/g, and good magnetic separation efficiency of 80%. The used ATP/CoFe(2)O(4) was successfully regenerated by NaOH and reused five times without a substantial reduction in TA removal and magnetic performance. Intermolecular hydrogen bonding formation and surface complexation were identified as the sorption mechanisms of TA by ATP/CoFe(2)O(4).