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Snapshots of magnesium-centred diborane heterolysis by an outer sphere S(N)2 process
Reactions of the β-diketiminato magnesium diboranate derivative, [(BDI)Mg{pinB(n-Bu)Bpin}] (BDI = HC{(Me)CNDipp}(2); Dipp = 2,6-i-Pr(2)C(6)H(3)), with N,N′-dialkyl and N,N′-diaryl carbodiimides provided the corresponding C-borylated magnesium borylamidinates. This reactivity occurs with the displace...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6624991/ https://www.ncbi.nlm.nih.gov/pubmed/31367321 http://dx.doi.org/10.1039/c9sc02087j |