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Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity
Silicon-tethered tetraynes possessing a 1,3-diyne moiety underwent consecutive hexadehydro- and tetradehydro-Diels–Alder reactions to give a series of fused polycyclic aromatic compounds containing a dibenzosilole skeleton. The benzene ring in the product acted as a 1,3-diene and reacted with the ac...
Autores principales: | Mitake, Akihito, Nagai, Rikako, Sekine, Ayato, Takano, Hideaki, Sugimura, Natsuhiko, Kanyiva, Kyalo Stephen, Shibata, Takanori |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6625486/ https://www.ncbi.nlm.nih.gov/pubmed/31367326 http://dx.doi.org/10.1039/c9sc00960d |
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