Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents

A family of non-ionic deep eutectic liquids has been developed based upon mixtures of solid N-alkyl derivatives of urea and acetamide that in some cases have melting points below room temperature. The eutectic behaviour and physical characteristics of a series of eleven eutectic mixtures are present...

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Detalles Bibliográficos
Autores principales: Suriyanarayanan, Subramanian, Olsson, Gustaf D., Kathiravan, Subban, Ndizeye, Natacha, Nicholls, Ian A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6627579/
https://www.ncbi.nlm.nih.gov/pubmed/31212745
http://dx.doi.org/10.3390/ijms20122857
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author Suriyanarayanan, Subramanian
Olsson, Gustaf D.
Kathiravan, Subban
Ndizeye, Natacha
Nicholls, Ian A.
author_facet Suriyanarayanan, Subramanian
Olsson, Gustaf D.
Kathiravan, Subban
Ndizeye, Natacha
Nicholls, Ian A.
author_sort Suriyanarayanan, Subramanian
collection PubMed
description A family of non-ionic deep eutectic liquids has been developed based upon mixtures of solid N-alkyl derivatives of urea and acetamide that in some cases have melting points below room temperature. The eutectic behaviour and physical characteristics of a series of eleven eutectic mixtures are presented, along with a molecular dynamics study-supported hypothesis for the origin of the non-ideal mixing of these substances. Their use as solvents in applications ranging from natural product extraction to organic and polymer synthesis are demonstrated.
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spelling pubmed-66275792019-07-23 Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents Suriyanarayanan, Subramanian Olsson, Gustaf D. Kathiravan, Subban Ndizeye, Natacha Nicholls, Ian A. Int J Mol Sci Communication A family of non-ionic deep eutectic liquids has been developed based upon mixtures of solid N-alkyl derivatives of urea and acetamide that in some cases have melting points below room temperature. The eutectic behaviour and physical characteristics of a series of eleven eutectic mixtures are presented, along with a molecular dynamics study-supported hypothesis for the origin of the non-ideal mixing of these substances. Their use as solvents in applications ranging from natural product extraction to organic and polymer synthesis are demonstrated. MDPI 2019-06-12 /pmc/articles/PMC6627579/ /pubmed/31212745 http://dx.doi.org/10.3390/ijms20122857 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Suriyanarayanan, Subramanian
Olsson, Gustaf D.
Kathiravan, Subban
Ndizeye, Natacha
Nicholls, Ian A.
Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents
title Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents
title_full Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents
title_fullStr Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents
title_full_unstemmed Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents
title_short Non-Ionic Deep Eutectic Liquids: Acetamide–Urea Derived Room Temperature Solvents
title_sort non-ionic deep eutectic liquids: acetamide–urea derived room temperature solvents
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6627579/
https://www.ncbi.nlm.nih.gov/pubmed/31212745
http://dx.doi.org/10.3390/ijms20122857
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