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Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface

Polymer brush layers can act as effective lubricants owing to their low friction and good controllability. However, their application to the field of tribology is limited by their poor wear resistance. This study proposes a strategy combining grafting and surface texturing to extend the service life...

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Autores principales: Shen, Ming-xue, Zhang, Zhao-xiang, Yang, Jin-tao, Xiong, Guang-yao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6630773/
https://www.ncbi.nlm.nih.gov/pubmed/31167341
http://dx.doi.org/10.3390/polym11060981
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author Shen, Ming-xue
Zhang, Zhao-xiang
Yang, Jin-tao
Xiong, Guang-yao
author_facet Shen, Ming-xue
Zhang, Zhao-xiang
Yang, Jin-tao
Xiong, Guang-yao
author_sort Shen, Ming-xue
collection PubMed
description Polymer brush layers can act as effective lubricants owing to their low friction and good controllability. However, their application to the field of tribology is limited by their poor wear resistance. This study proposes a strategy combining grafting and surface texturing to extend the service life of polymer brushes. Surface microstructure and chemical composition were measured through scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). Water contact angles were measured to evaluate the surface wettability of the grafted silicon-based surface texture. Results showed the distinct synergistic effect between polymer brushes and laser surface texturing (LST). The prepared polymer brushes on textured surface can be a powerful mechanism for friction reduction properties, which benefit from their strong hydration effect on the lubrication liquid and promote the formation of a local lubricating film. Moreover, the wear life of polymer brushes can be immensely extended, as micro-dimples on the textured surface can effectively protect the polymer brushes. This study presents a method to enhance the load-bearing capacity and wear resistance of the grafted surface of polymer brushes.
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spelling pubmed-66307732019-08-19 Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface Shen, Ming-xue Zhang, Zhao-xiang Yang, Jin-tao Xiong, Guang-yao Polymers (Basel) Article Polymer brush layers can act as effective lubricants owing to their low friction and good controllability. However, their application to the field of tribology is limited by their poor wear resistance. This study proposes a strategy combining grafting and surface texturing to extend the service life of polymer brushes. Surface microstructure and chemical composition were measured through scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). Water contact angles were measured to evaluate the surface wettability of the grafted silicon-based surface texture. Results showed the distinct synergistic effect between polymer brushes and laser surface texturing (LST). The prepared polymer brushes on textured surface can be a powerful mechanism for friction reduction properties, which benefit from their strong hydration effect on the lubrication liquid and promote the formation of a local lubricating film. Moreover, the wear life of polymer brushes can be immensely extended, as micro-dimples on the textured surface can effectively protect the polymer brushes. This study presents a method to enhance the load-bearing capacity and wear resistance of the grafted surface of polymer brushes. MDPI 2019-06-04 /pmc/articles/PMC6630773/ /pubmed/31167341 http://dx.doi.org/10.3390/polym11060981 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Shen, Ming-xue
Zhang, Zhao-xiang
Yang, Jin-tao
Xiong, Guang-yao
Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface
title Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface
title_full Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface
title_fullStr Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface
title_full_unstemmed Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface
title_short Wetting Behavior and Tribological Properties of Polymer Brushes on Laser-Textured Surface
title_sort wetting behavior and tribological properties of polymer brushes on laser-textured surface
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6630773/
https://www.ncbi.nlm.nih.gov/pubmed/31167341
http://dx.doi.org/10.3390/polym11060981
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