Formation of an imidazoliumyl-substituted [(L(C))(4)P(4)](4+) tetracation and transition metal mediated fragmentation and insertion reaction (L(C) = NHC)

Tetracationic cyclo-tetraphosphane [(L(C))(4)P(4)](4+) as triflate salt (3[OTf](4)) (L(C) = 4,5-dimethyl-1,3-diisopropyl-imidazol-2-yl) is obtained in high yield from the reduction of [L(C)PCl(2)](+) (4[OTf]) with 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine (6) and represents the first salt of the c...

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Detalles Bibliográficos
Autores principales: Schwedtmann, Kai, Haberstroh, Jan, Roediger, Sven, Bauzá, Antonio, Frontera, Antonio, Hennersdorf, Felix, Weigand, Jan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6640194/
https://www.ncbi.nlm.nih.gov/pubmed/31391910
http://dx.doi.org/10.1039/c9sc01701a

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